Just tested, both signals on each XLR generates 2.065V (expected) and obviously 4.13V if you compare them to each other using a 1kHz sine wave input.
The TRS to RCA cable is also outputting perfect 2.065V on the same wave.
I tested again with a louder white noise source and still, on the same output level on the E50 DAC the Aiyima consistently produces 10-12db louder output.
10dB louder at the same input level should be exactly per measured gain (19dB vs 29dB). If you want to make PA5 play louder, you'll need to feed it a higher level input. If your DAC can't produce it, then you'll need a preamp that can, or another DAC that can, or a different amp.