I only know the opinions from the person who built tube amps, he said that toroidal transformers should be avoided since they spread distortion.
He also was making his own transformers very carefully, with some special cores and winding technics. But as I said, that is and opinion. I believe that many factors matter in tube amps. In power supply capacitors are probably even more important, their total capacity, ESR, by-pass caps etc.
So if you want to build good tube amp for listening make no compromises in the power supply. Good quality oversided transformer is important. As far as polish toroids they are probably good in price/performance ratio but the best sounding tube amps I heard did not used toroids, as far as KT-88 concerned the best I heard is Air Tight ATM-2. This is SOTA amplifier, however not the power beast like some Audio Research or Jadis...