IMD (intermodulation Distortion) is one of the main culprits that can make amplifiers sound 'bad'. It's heavily reliant on harmonic distortion (THD - total harmonic distortion plus noise), but not in any easily calculated way. Any amplifier that has harmonic distortion, has intermodulation distortion as well, and the converse is also true. Harmonic distortion (as its name suggests) generates harmonics of the original signal. A 1kHz tone will have 2kHz, 3kHz, 4kHz, 5kHz (etc.) harmonics, but in some cases the even harmonics are suppressed (2nd, 4th, etc.). Push-pull amplifiers (regardless of topology) fall into this category, and have predominantly odd harmonics only. This is never true in real life - all amplifiers, regardless of what they use as an amplifying device, have both odd and even harmonics, but the even harmonics can be below the noise floor. Just as it's impossible to design an amplifier that presents only the second harmonic, all amplifiers will have some of every harmonic present. Hopefully, most will be far enough below the noise floor that the distortion is not intrusive.
Unlike harmonic distortion, intermodulation generates frequencies that are not harmonically related. This makes them far more objectionable, because the frequencies generated are unrelated to the input frequencies. It's important to understand that the process of distortion (of all forms) is simply due to non-linearity. The amplifying device does not 'generate' the new frequencies directly, but they are an inevitable by-product of distortion. When the shape of a waveform is changed, the harmonics (and/ or other frequencies) are created simply due to the physics of waveforms. A pure sinewave has (by definition) no distortion, and consists of a single frequency - the fundamental. Distortion is due to non-linearity, and that modifies the shape of the waveform.