You don't "convert" PCM to DSD in postprocessing. You'll be disappointed. It's not like that, because you start with insufficient audio information and are dependent on your processing software, which - I'm sorry - won't be up to the task like any other software tasked with adding information without degrading the total. Is DSD "better?" I dunno. I listen to DSD, in genres beyond my usual because Deep Purple didn't record in DSD, and the recording process is vital when it comes to A:B comparisons. It's either DSD in the studio, or irrelevant.
Stuff recorded in DSD, in the wholly unprofessional opinion of somebody who's looking back at his 60th birthday and using speakers which cost <$1000, is noticeably better to me in A:B with high-bitrate lossless PCM, I freely admit bias, though, unlike some who've never heard the term "anecdote."