I have a few questions, like why you are not using the built-in aps of the 8500H, but some tips for getting better sound.
Modify the sound curve via the JSON file from the multi-EQ app, I'm using the Toole+bass curve from AVSForum.
Disable the following surround parameters from the denon (Cinema QE and Loudness).
Changing the audyssey adjustment frequency just means the frequencies above that are going to remain as is and not touched by the target curve. I have this set to 500Hz as well.
I set my crossover to 60Hz for my system and this sounds good, but did run it at 90Hz for a while. Still testing.
Some details here on how to manually edit the curve:
https://www.avsforum.com/threads/an...r-tweaking-audyssey-multeq-app-files.3006886/
The last couple of pages show how to edit the curve in a browser/JSON editor so you don't need to use the software.