How accurate is your measuring device? And how fast does it respond? "Peak" power can be tricky to measure (and record).
A typical class AB amp is probably somewhere around 60% efficient and that may be high depending upon what else is in the component. At 60%, you need about 1/0.6 = 1.7x the input power so 80 W yields about 48 W or 24 W/ch output so yes that seems in the ballpark. The SPL depends upon your speakers, your distance from them, room effects, etc. A very rough ballpark can be gleaned from an online calculator such as this one:
Peak SPL Calculator . A pair of speakers with 90 dB/W/m sensitivity at 8' away will produce about 100 dB SPL driven by 24 W each. That is pretty loud to me but I've no idea what you consider "loud but comfortable". And don't forget most of the power is probably in the lower frequencies where it is easy to play at much higher SPL before it sounds "loud" (
https://en.wikipedia.org/wiki/Equal-loudness_contour ).
HTH - Don