My understanding with that glass windmill thingy is that there is not an absolute vacuum in there, and the dark sides of the vanes absorb heat from the sunlight and slightly push gas molecules away from them, and the force of the molecules as they launch from the vanes pushes them enough to spin the device. The white sides of the vanes do not heat up as much, so the imbalance in heating allows an unbalanced force to develop on the vane's paddles, causing rotation to happen. I also recall seeing an experiment in which one of these globes was fitted with a nipple to allow a vacuum pump to be connected to it. At first, the air-filled globe's spinner did not rotate. The pump was turned on, and after a while, the spinner started to move. As the pump continued to run, the spinner came to a standstill.