How can someone calculate if the amplifier they have can deliver sufficient voltage when needed, and sufficient amperage when needed? The typical statements I see is that a speaker requires a high current amplifier when in a low impedance state and a high voltage amplifier when in a higher impedance state. So how can someone test or confirm through documentation if their amp is capable of producing both the amperage and the current required for the range of their particular speaker? Power ratings by themselves seem insufficient to differentiate between the two.

Unfortunately you cannot, because amps are typically just rated in WPC into 8 and 4 Ohms. The 4 Ohm rating, if given, would indicate the current capability and the 8 Ohm rating would indicate the voltage capability but only to an extent.

As I posted elsewhere, amps should have been rated more usefully by voltage and current, not power. For example, if an amp rated 100 W/150 W 8 Ohm/4 Ohm is rated instead:

Max. voltage: 28.3 V, Max. current: 5 A, then we can calculate the Max. power output = 28.3 X 5 = 141.3 W and it would be achieved if the load is a 5.65 Ohm resistor by simply using the power formula:

P = (V^2)/R, or (I^2)*R, or V*I

I am simplifying things a lot just to make it easy to follow. In the real world, loudspeakers are not resistors and amplifiers can be rated in many different ways such as continuous indefinitely (very few amps are rated that way), "continuous" to mean just tested with a continuous sine wave, or for a specific duration, short term rating, e.g. 20 ms, 200 ms, 2, 5, 10 minutes etc.... you get the idea. Manufacturers don't, or won't tell you all those things either.

Also note that loudspeakers are voltage sensitive device, the spl it produces is proportional to the input voltage, as long as the amplifier driving it is not current limited. So when we say the speaker takes 100 W, it actually may take/consume much less, as a good part of it would be dissipated in the amp's output stage, that's why the heatsinks and fans are there to keep the output devices from overheating.