AHA!
I think I have figured out how to enable the wasapi exclusive/bypass feature of Amazon music HD. It's not obvious! This feature enables you to play Amazon Music HD selections at "HD" or "Ultra HD" resolution (for tracks so-labelled) and auto-switches the Amazon playback bit depth/sampling rate to the native resolution of the source recording, without upsampling or downsampling. "Exclusive Mode" does this by bypassing the regular Windows 10 audio mixer which otherwise will constrain playback to lower resolutions, or in some cases, force upsampling to higher resolutions, depending on Windows settings.
1. First, in Windows 10 you have to go to Settings/Sound and select your DAC or other output device. Then for that device, choose Device Properties/Additional Device Properties and select the Advanced tab at the top. In the Advanced tab, check the two boxes enabling exclusive mode. ALSO: on the top of the same tab menu, choose your device's maximum bit depth/sampling rate (e.g. 24/192) for the "shared-mode" Windows default sampling rate. Even though you will be in exclusive mode, not shared mode, Amazon interprets that value as the maximum for the device in Amazon's auto-switching of the sampling rate in exclusive mode. (Perhaps not its intended use! But perhaps a practical ceiling rate for Amazon's auto-switching if it is not set too low.) So set it to 24/192 or to something that is your device's true maximum. Amazon will not oversample a lower-resolution recording up to that ceiling; it will just auto-switch to the correct rate. But if you set the default/shared-mode rate too low (e.g. 16/44.1), Amazon will downsample a higher-resolution recording to that rate in playback.
2. In Amazon Music HD, open the settings menu (little head in a circle in upper right corner), Under the "Playback" heading, toggle exclusive mode to On to allow exclusive playback.
3. Then when actually playing your first music selection of a listening session in Amazon Music HD (and apparently ONLY in that screen), click the little speaker image/icon at the lower right corner to display the "Available Devices" list. As a result of the prior step, there should be not only a list of available devices, but also an "Exclusive Mode" toggle below it. Make sure the correct device is checked and toggle the Exclusive Mode on. I believe you have to do that last step EACH time you open Amazon Music HD or change playback devices ... the setting is not "set and forget", and I imagine this is so that when you leave your listening session, Windows audio will work normally for other Windows apps, instead of being bypassed.
If you do all of the above, the "volume" slider at the bottom of the Available Devices menu grays out and is disabled, seemingly validating the wasapi exclusive-mode bypass of the Windows mixer. Or you can click the little "HD" or "Ultra-HD" indicator on the bottom left of the Amazon playback menu for that selection to see the playback rate as well as the recording's native sampling rate and the "device limit" set in step 1 above. (Thanks DIYAUDIONUT for that tip!)
The above set of steps is not explained clearly anywhere that I have seen ...