FWIW, I am adding a second sub. I have done experimenting with REW Room Sim, and got the following. I have no acoustic treatment in my room.
First, no subs:
View attachment 457634
One sub:
View attachment 457636
Two subs both at side of main speakers:
View attachment 457638
Finally, and the option I am going to start with, two subs diagonally opposite:
View attachment 457639
Interestingly, two subs with each at the side of the main speaker appears to add nothing compared to a single sub. Diagonally opposite seems to work best, in theory at least.
I'm going to get two MJ Acoustics subs (from here in the UK), mainly because they have a very good app that helps with phase and gain setting.