My RME DAC connects to my stereo floor speakers via the rear balanced XLR outputs and to my DCA Stealth headphones via the front balanced Pentaconn connector. The 12V trigger powers my amp on and off with the DAC, which I really like. I rarely listen with headphones, but when I do, I usually turn off the amp since it runs somewhat hot as a class A/B design and warms the room in the summer. I keep my house around 68F/20C, but this particular room can climb to 74F/23C when I’m gaming with my high-end PC, 38-inch monitor, OLED TV in the background, and the stereo amp running.
Ideally, I’d like a way to disable the 12V trigger remotely, rather than having it tied directly to the DAC’s power, or have the amp automatically turn off when I switch to headphones and power back on when I switch back. As it stands, if I turn off the amp while the DAC is on and the trigger cable is connected, the amp won’t power on again until I turn off the DAC, manually power on the amp, and then restart the DAC to resync. Granted, this could be an issue with my amp, but there is no way I'm going to replace the amp as a solution. It is not that big of a concern, just looking for a convenient solution.
Edit: I always have my headphones and amp connected to the RME DAC. I normally use the DAC's remote to control everything.