Are you needing multichannel, or just stereo? PCM Front (or one of the sliders, anyway) controls the output from the two RCA sockets so it should be fine for stereo.Eh, pity.. That means volume control won't work with Volumio. Anyway, thank you!
Will you be running Pulseaudio? I would have thought it very unlikely that it isn't possible to set something up to do what you want. So many configuration files! e.g. in /usr/share/alsa and /usr/share/pulseaudio - I find it a bit mind boggling. You can maybe set up a virtual 'loopback' driver to act as a fake device and configure the volume level to be copied to all the channels, etc.