If you want build something and it is for speakers and have little to no experience perhaps start with encasing a class-D amp and its power supply using the better class-D amps.
The ACA is not very powerful. Depending on your speakers, the size of the room they will be used in and how loud you occasionally want to play the ACA might disappoint.
Sure you would have built something (populated a board) and made a casing for it but would likely be a waste of money.
The Neurochrome kits are more likely not to disappoint.
I would not recommend to go down the tube-amp build route as there are lethal voltages involved and when tinkering with it a charged capacitor is not a good place to be.
My first build was an ACA. I just bought the boards, then sourced the components separately so I didn't have a lot invested in them. I don't think I spent over a couple hours listening to it. I've always wondered if I did something wrong based on the glowing reviews it receives. Even at low volumes I wasn't impressed. Although, one time I fed it with the 02 Headphone amp on high gain as a preamp and thought it sounded better.
My second build was a single ended tube amp. I don't know if a lot of it was the fun of building it but when I was done it sounded exquisite. Then I chased tweaks, capacitors and tube rolling down the rabbit hole and it never sounded the same. With one set of tubes the highs would sound good, with another the lows sounded good. Whenever I turned it on I'd think it sounded great, but I don't know if it was always in the back of my head that a different tube might sound 'better' but I was never happy long term with it. And when a song would come on that I'd like and turn it up I could hear it struggling. Even a low powered SE like it used 90 watts continuously and put out a fair amount of heat in the summer. Now that I run the stereo 12-16 hours a day and use music to drown out the neighbors, it just doesn't seem optimal.
That amp was in a wood case (treated with fireproofing) so I never got a bad shock off of it. However one I did get careless with one that I used in the garage and sent 400v down one arm, through my chest and out the other. That did not feel good and I probably should have seen someone about it.
I built Rod Elliott's PA3 and I still enjoy its 'smooth' sound. I don't think it is really a high fidelity sound but it is quite pleasing. Only when I turn it up do I find it not as good.
Later after a few other builds I did the Akitika GT-102. To me that is the perfect beginner DIY amp. Bulletproof instructions, no sourcing of parts, no drilling, no figuring out power supplies or adding speaker protection or and of the other tasks that most builds take. It sounds good.
A few more builds down the road and I finally did the Modulus-86. The boards and instructions were very good, but it requires sourcing a case and power supply and speaker protection. Then fitting it all and making sure it is solidly and safely constructed. To me it seems to sound a bit better than the GT-102 but I may be imagining that. I generally found myself listening to this amp the loudest out of any of them. I wouldn't think about it but would notice after awhile that I had it pretty loud. It is clear and strong at higher volumes.
I also build Rodd Elliott's P101A and it is clear and punchy but I'd kind of like a tone control to up the low end a bit on it.
And then finally, after all those years, all those builds and all that money.... I've decided I really like having a remote control for the power, volume and input switching, plus tone controls are nice. So, tomorrow a Yamaha R-N600A is due to arrive. I really enjoyed the building, the planning, the sourcing parts on the DIY builds. I find the process very Zen and I do miss it. However, looking back, I could have bought a really impressive 'forever' amp for the money I've spent. Instead I have a tote full of completed amp boards and a few completed amps in cases that have no resale value.