Pure direct turns off all DSP in the AVR - so you are not using Audessey if you are using pure direct.Played pure Direct, with the same Audessy settings i had been using for years....the music was fatguing.
"Fatiguing" is nearly always a frequency response issue. In this case without any room correction, this is most likely due to speaker/room interaction - not the amp. The amp (Like all halfway decent amps) has flat frequency response. Certainly trying to solve this by changing the DAC will only take you on an expensive highway to nowhere.
So if you want to solve the fatiguing problem your best bet is to get a good working room correction, with a target curve that suits your preference. I used audessey one to achieve this. My system sounds stunning now, whether for music or movies - using the same Audessey set up.
Certainly it is worth putting in some work to get this working. It is cost free if you already have the Denon/Audessey phone app - only about £$20 if you don't.
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