Room gain and acoustics may let you believe in 25 Hz extension, but ...
Erin's review and measurements state extension to 40 Hz.
The data also shows a sudden rise in distortion of 20 dB below 40 Hz.
You said, you want to maximize SPL and reach down into infrasonics?
Which sub(s) do you have, that would possibly be able to handle that?
Anyway, with the above goals, your only option is to high pass your speakers at around 40 Hz and let at least a pair of beefy subs handle the lows.
PEQ filters alone will likely not cut it for your goals, you really need to follow some of
@OCA excellent advice and use more serious DSP to extract all their potential within your room constraints.
EDIT, posted the following before seeing your newer post...
And, why are you so sold on RME, if i.e. a much cheaper Topping DM7 8 channel DAC is very close in measurements, read inaudible, on skimming available data?