The best isolation i witnessed (25 years ago) is rammed earth (a mixture of sand and clay), or rammer earth mixed with straw. It's also a very good absorber, heat isolation/thermal mass and humidity regulator btw. The disadvantage is that it needs to be thick to be stable and hard to make mechanised (a lot of handwork) and you need to protect it against rain when it's an outside wall with a waterproof layer of other material (lime plaster in the place where i saw it. And it's not structural strong, you need a frame of wood, concrete or steel to support it.
I've recorded some Morrocon Zenati folk music in a rammed earth house in the east of Morroco, and altough the room was not acoustic treated at all, it was a very good acoustic, and little eq was the only processing needed That was certainly partly because of very good musicians who always play unamplified and balance themselves, but certainly also because of the room acoustics (wood ceiling, rammed earth floor and walls with little windows with no glass). Even with that no glass, the noise from the village was much damped inside, in a matter it did not disturb the recording. That room was better than most recording studio's i've been in (and i've been in good ones). That cd did sell well in the region and bordering region of Algeria (that has a similar Zenati Berber culture).
But to implent that here, is a bit difficult. What i learned there is that you need enough mass to damp low vibrations, and a porous surface that is also solid to absorb high. I'm not a physician or achemist who can make the right stuff and apply it perfectly right, but i can easely see if material has good specs to damp or not and what should be enough to do the job roughly.