Just to add to Amir's post, a sound card can be used for measuring high voltages, provide you make yourself a suitable attenuator which ensures that the audio card never clips. An external USB audio card with input level metering is useful, but at very least a 'clip' light is essential. In my own case, I've built a set of dummy loads with variable attenuators so I can measure the output of power amps up to the limit of the dummy load power handling, and somewhat more if I keep measurement time short so the loads don't overheat
One can of course calibrate the input of the sound card and use a calibrated attenuator to make it suitable for measuring voltages, but I find it a lot easier to use an external audio millivoltmeter for that function, and use the sound card for relative measurements, like Distortion, frequency response and S/N, none of which require an absolute voltage measurement. Monitoring the waveform on an oscilloscope I think is also essential with any measurement, whether with a sound card or a dedicated meter, as it's too easy to be fooled by a clipped signal.
S.