The specs of the UCA202 are pretty mediocre. You might be somewhat limited by the ADC.
In any case using what you have already run the match on the recorded file. First go into settings of Deltawave (click on the gear symbol in the upper right corner). It will open a page with lots of settings to monkey with. In this case look at the lower left corner. Click Level EQ and next to it Phase EQ. Close the window. Run your comparison. DW will now correct frequency response errors, and phase errors. Sometimes this will improve the null results considerably. If so this tells you the main problems with a better null are simply FR and phase effects. Which aren't anything exotic.
Also Deltawave works best with 2 to 3 minutes of a track to work with. It will even usually work pretty well with 1 minute. I don't know how long a recording you made, but get it a bit over 2 minutes for future testing.