You're right that preference for tubes doesn't indicate superior technology. BUT tubes produced lots of 2nd/3rd order distortion that was less disagreeable than a relative preponderance of higher order harmonics. Ironically tube amps often have lot of high order harmonics but these are outweighed or masked by the 2nd/3rd harmonics.I bet the list of shortcomings for early solid state gear was far shorter than early tube gear. Tube fans obviously like the "Tube" sound, which is fine. This isn't however, indicative of a superior topology.
S/S technology has advanced greatly since the '70s. In audiophile terms S/S was hindered by the myth that negative feedback is a BAD thing.. This idea was propounded by the likes of Nelson Pass and others. The reasoning was that substantial negative feedback produced higher order harmonic. This is TRUE, but sufficient negative feedback reduced ALL forms of distortion including high order ... that is, the solution to the problem of using little feedback is using a lot of negative feedback. Today's S/S amps have huge negative feedback and ultra-low distortion.
In my observation some tube fans, (not all), are moving away from that technology, finally realizing their original reason for preferring tubes has gone away.