There is something that looks like it has an external tooth star washer. However, the devil is in the details. If the washer is held in place - i.e. the head of the screw is torqued but the nut is held in place - the teeth may not reliably bite through paint since all the teeth would do is compress the paint. However, if the nut is torqued while the screw is held in place, the washer will probably spin-and-bite at the same time which is what you want.I believe but could be wrong, that Buckeye does use some type of locknut on the underside of the ground connector. Maybe @Buckeye Amps can confirm or correct me on this?
More importantly, why does it look like raw wire strands are sticking out from under the nut?