Noob understanding here, but for just measuring to tweak physical room treatments, no need to climb the steep Acourate learning curve, REW is the standard, much better documented, huge help community.
The point of Acourate is generating complex filters for active Digital room correction.
It would be more accurate to say that REW is primarily a measurement tool which can be pressed into service for creating minimum-phase DSP, and Acourate is a specialized linear-phase DSP and simulation tool. Acourate is also better at designing filters for multi-driver active systems. Whilst Acourate can take measurements, its focus is more on filter design so it lacks a few of REW's features, for e.g. no spectrogram, no waterfall, no CSD, etc. But it can also take measurements that REW can't, for e.g. you can create your own test signal and use it in Acourate's loopback recorder.
If you want linear-phase with REW, you will need rePhase. Whilst it IS possible to do everything that Acourate can with REW/rePhase, it would be incredibly tedious. Let's say you have an 8 way active speaker system, and you want to generate DSP crossovers for each driver, with individual driver corrections and time alignment.
With Acourate: one step to generate crossovers. Then measure each driver, and use the driver linearisation macro (two steps for each driver). Measure all the drivers together, then do room correction (5 steps).
With REW/rePhase: generate each crossover individually (one step for each driver). Measure each driver, then export to rePhase. Generate the driver correction, then export back to REW. Now you have a problem: REW has no built-in convolver. How are you going to measure a 4-way speaker with all the drivers playing together? One option is to remeasure each driver individually with a time reference and then sum them. Or you will need another third party software. Write a .CFG file for your convolver, then load all the filters you created in rePhase. Measure the 4-way speaker, then invert over a target curve. I have lost count of how many steps this requires. Once you have your inversion, convolve the inversion with each individual filter (8 of them). Then either re-measure or convolve each filter with the measurement to check the step response for pre-ringing, once per driver.
It would take you more than a week, and that's assuming you don't make any mistakes and have to start again. Acourate is not the fastest, but I would be able to complete a project from scratch in half a day. Other options are even faster, e.g. Audiolense lets you complete the whole project from start to finish in less than an hour since even more of the process is automated. With Audiolense, you spend most of your time on the setup screen telling it what you want, then you set up your mic and walk away. When you come back, there are a few more dialog boxes, then your filters are ready.