Don't start there! By adding a super tweeter, you are essentially taking on a speaker design task, it is not just plug-and-play. Some issues to contend with:
1) Drivers more than 1/4 wavelength apart interfere with each other, more so as they get further apart. Phase differences can increase the problem. 1/4 wavelength at 10,000 Hertz is about 1/3 of an inch, so you will have that problem.
2) Diffraction from cabinet edges and surfaces have large effects at high frequencies. If you do not model or measure them, at multiple angles, you will have additional errors.
3) Test your hearing. Can you hear 16K at all? If you are over 30, probably not.
4) Since the concept is problematic at several levels, if you want to experiment, try a cheaper tweeter first and see if it is better, worse, or imperceptible. Have someone help you with a blind test so your expectations do not effect the result.
You could try a couple of these:
Dayton Audio ND16FA-6 5/8" Soft Dome Neodymium TweeterDon't let the low price fool you! This versatile tweeter is a huge step above the average "budget" tweeter. Conceived with line array thoughts in mind, it is finally possible to achieve the inter-driver spacing needed to minimize comb...
www.parts-express.com
with a 1.5uF capacitor in series as a start. Try some double-sided carpet tape to stick it as close as possible to your existing tweeter. If it is too loud, add an L-pad or a resistor.
If you let us know what your speakers are, we could help more. If this is for the Dynaudio speakers in your signature, they should have no problem reaching higher than 16K on their own, and certainly would if EQ'd. Using EQ would avoid all the problems I mentioned with adding a supertweeter.