@Roland68
SUCCESS!!!!
NO popping at all. I tested with my PA5 II under the conditions I heard the popping, and then with the A7 connected.
Keeping the PO100 Pro, and I can now use the A7 in its intended place. I can't set the bit/sample rate higher than 32-bit/192kHz on my Mac's MIDI app, but I don't care, it all sounds fantastic!
Edit:
Looking more into USB DDCs, it turns out I already had one -- two, in fact: the Topping D10s. Apparently the Topping D10s can act as a USB DDC when using the optical output (bypassing the D10's DAC, and acting as a bridge). It's even in the Marketing material for the device on the Topping site. I'll still keep the PO1000 Pro, but if there's a compelling argument to use the D10s over the PO100 Pro, I wouldn't mind hearing pros/cons for either. The only differences I am aware of are the D10s is 24-bit/192kHz via optical where the PO100 Pro is 32-bit/192kHz. D10s uses XMOS XU208, the PO100 Pro uses the XMOS XU316. I'm sure the argument can be made that those differences would be utterly inaudible. The one advantage the D10s has over the PO100 Pro is its size. I've noticed with the PO100 Pro that the cables really want to tell this thing where to sit.
At any rate, the A7 is now fully set up in its proper home, and I spent most of the evening finally enjoying the amp. Man, it's a good amp. Compared to the PA5 II, when the volume dial is set at the same 9 o'clock position, the A7 is noticeably louder, and it's incredibly clean. No pop from turning on the unit, but the tiniest of pops when powering down (normal behaviour IMO, and nothing I am concerned with). The powering down pop with the PA5 II is slightly more audible, so there is an improvement, there. I have it set up, now, with my DAC in preamp mode, and the volume bypass enabled on the A7. The only minor "complaints" (and I use the term in the loosest sense) is the volume control on the amp is a bit janky up until you hit the 9 o'clock position -- This is mentioned in the manufacturer's information, so I was aware of the behaviour already. I usually prefer to use the amp to control the volume, but it seems like I do have a bit more control over the volume using the DAC instead, so that's how I will leave it.
I would almost like them to release a version of this amp without any volume control at all -- just a power button on the front, and maybe an optional gain toggle switch on the back with the usual balanced/RCA inputs, and a 12v trigger input (looking at you,
@3eaudio 
).