That Marantz features only rather small amp power. Quality of sound depends on if you are comfortably within that area. Or if you are pushing it. You only have 2.0 speakers on that amp?So I have been reading about this amp a lot and it seems to be very good. I currently have a Marantz Cinema 70 which is rated as a poor amp on but it has pre-outs (it sounds good to me to be honest). If I where to connect the A5 to the pre-outs what would be the audible difference between the two? My speakers are Triangle Comete 40th edition and I never listen at very loud levels.
An external amp like the A5 has more power then the Cinema 70 and allows you to go louder and have good reserves for transients and peaks. But what you will be hearing is still the pre-amp section of the Marantz with the sound quality it produces, it's noise and distortion level. I don't think that's bad sound, but the external poweramp won't change anything about it either.
Other things the A5 can do for you: take the load off the Marantz and leave it running cooler. It depends on the specific Marantz how good that works, if the amps can be turned off completely or will be idling nonetheless when you use the pre-out signal.
The A5 allow you to use two inputs. Obviously RCA in with high gain for the AVR. But you can also populate the balanced inputs, which have a lower gain. And switch to that input with a press on the front button. Whatever you put there (DAC, Streamer, ..) can use the amp and the speakers without the Marantz.